| Paper No. 37-0 | |||||||||||||||||||||||||||||||||||
| THE COMPOSITION OF TERTIARY SEA WATER | |||||||||||||||||||||||||||||||||||
|
ZIMMERMANN, Heide, Dept. of Earth and Planetary Sciences, Harvard Univ, 20 Oxford St, Cambridge, MA 02138, zimmermann@eps.harvard.edu, HOLLAND, Heinrich D., Earth and Planetary Sciences, Harvard Univ, 20 Oxford Street, Cambridge, MA 02138, holland@eps.harvard.edu, and HORITA, Juske, Oak Ridge National Lab, PO Box 2008, Oak Ridge, TN 37831-2008
The composition of fluid inclusions in halite in four Tertiary and one Cretaceous marine evaporite shows that the Mg concentration of sea water increased from 32 mmol/kg sw to its present value of 53 mmol/kg sw during the past 60 m.y. They also show that mK+ was essentially constant at 10 mmol and that mMg+2 + mCa+2 ~ mSO4-2 + 35 mmol during this period. The values of mCa+2 and mSO4-2 can be deconvolved if the product mCa+2*mSO4-2 is assumed to have been constant during the Tertiary. Although absolute constancy of this product is unlikely, the assumption leads to a mMg+2/mCa+2 ratio in early Tertiary sea water that is consistent with the estimated value at the transition of aragonite to calcite seas and with an estimate of the mMg+2/mCa+2 ratio in sea water based on the Mg content of the foraminifer O. umbonatus (Lear, Elderfield and Wilson, 2000).
| |||||||||||||||||||||||||||||||||||