Paper No. 136-2
Presentation Time: 8:20 AM-8:35 AM
PARTITION COEFFICIENT ROBUSTNESS: IMPLICATIONS FOR PARTITIONING TRACER TESTS (PTTS)
DIVINE, Craig E., Geology and Geological Engineering, Colorado School of Mines, Golden, CO 80401, cdivine@mines.edu and MCCRAY, John E., Geology and Geological Engineering, Colorado School of Mines, Golden, CO 80401-1887

The partitioning tracer test (PTT) is a promising new characterization method for locating and quantifying subsurface nonaqueous phase liquid (NAPL); however, relatively little work has been completed to quantitatively evaluate potential error sources for this technique. For example, the NAPL saturation calculated from a PTT is based upon the observed retardation of the partitioning tracer and the tracer’s NAPL-water partition coefficient. For most sites, the released NAPL is a waste and/or mixture of solvents or fuels; therefore, its composition may vary significantly both spatially and temporally (especially after remediation efforts). However, tracer partition coefficients are typically determined in batch tests using laboratory-grade NAPL or site NAPL collected at discrete locations and times. Consequently, the partition coefficients used may be inappropriate, yielding an inaccurate estimation of NAPL saturation. For tracers with robust partition coefficients (i.e., partition coefficients that are relatively insensitive to NAPL composition), these estimation errors are minimized. PTT modeling and error propagation are used to evaluate potential error and bias in PTT interpretation related to partition coefficient error and robustness.

2002 Denver Annual Meeting (October 27-30, 2002)
Session No. 136
Characterization, Attenuation, and Remediation of Subsurface Contaminants in Heterogeneous Chemical or Physical Settings I
Colorado Convention Center: A201
8:00 AM-12:00 PM, Tuesday, October 29, 2002
 

© Copyright 2002 The Geological Society of America (GSA), all rights reserved. Permission is hereby granted to the author(s) of this abstract to reproduce and distribute it freely, for noncommercial purposes. Permission is hereby granted to any individual scientist to download a single copy of this electronic file and reproduce up to 20 paper copies for noncommercial purposes advancing science and education, including classroom use, providing all reproductions include the complete content shown here, including the author information. All other forms of reproduction and/or transmittal are prohibited without written permission from GSA Copyright Permissions.