2004 Denver Annual Meeting (November 7–10, 2004)
Paper No. 55-10
Presentation Time: 1:30 PM-5:30 PM

KINETICS OF THE REACTION DOLOMITE = PERICLASE + CALCITE + CO2: AN EXPERIMENTAL INVESTIGATION OF REACTION AND FLUID TRANSPORT IN ROCK CORES

DEANGELIS, Michael T.1, LABOTKA, Theodore C.1, COLE, David R.2, FAYEK, Mostafa1, ANOVITZ, Lawrence M.1, and LORDO, Kathleen M.1, (1) Department of Earth and Planetary Sciences, Univ of Tennessee, Knoxville, TN 37996, mdeangel@utk.edu, (2) Chemical Sciences Division, Oak Ridge National Lab, 1 Bethel Valley Rd, Oak Ridge, TN 37831-6110

Contact metamorphic analog experiments were conducted using non-siliceous dolomite rock cores to study the extent of reaction and fluid transport resulting from breakdown of dolomite to produce calcite + periclase.  This reaction results in a reduction of the solid volume of the rock and production of CO2.  Experiments were carried out using a cold-seal hydrothermal apparatus. The dolomite rock cores were sealed in gold capsules with an aliquot of isotopically enriched water of composition H218O or HD18O0.516O0.5. The samples were held at a P=100 MPa and T=650 – 750 °C for durations ranging from a few days to a few months. After experimentation, the cores were sectioned and examined by EMP and SIMS techniques.  Reaction rates were calculated, and for experiments at 700 °C a reaction rate of 2E-11 mol/cm2s was determined.  Extent of reaction was determined by both point counting and by measurement of reaction produced CO2 and was found to have a log-linear relationship to time which gives an apparent first-order rate constant of 1.4E-7s-1.  SIMS ion imaging shows extensive enrichment of 18O within reaction products and along dolomite grain boundaries and fractures.  Isotope-ratio analyses along traverses within dolomite grains show an enrichment in 18O from core to rim.  The lack of Fe, Mn, and Sr mobility within dolomite near reaction grain boundaries indicates that diffusion rather than recrystallization is the primary mechanism for 18O exchange.  Experiments on reaction rates of dolomite breakdown in mixed volatile fluids with powdered starting materials are difficult to evaluate because of the presence of quench phases.  Our experimental results indicate that rock core experiments are effective in determining surface and transport kinetics.

 

2004 Denver Annual Meeting (November 7–10, 2004)
General Information for this Meeting
Session No. 55
Modeling Grain-Scale Processes in Metamorphic Rocks (Posters)
Colorado Convention Center: Exhibit Hall
1:30 PM-5:30 PM, Sunday, November 7, 2004

Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 144

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