GSA Annual Meeting, November 5-8, 2001

Paper No. 0
Presentation Time: 8:45 AM

THE APPLICATION OF CENTRIFUGE MODELING AND LASER ABLATION ICP-MS TO QUANTIFY RETARDATION IN CLAY-RICH AQUITARDS


MUISE, Jason1, HENDRY, M. Jim2 and KERRICH, Robert1, (1)Univ Saskatchewan, 114 Science Pl, Saskatoon, SK S7N 5E2, Canada, (2)Geological Sciences, Univ Saskatchewan, 114 Science Pl, Saskatoon, SK S7N 5E2, Canada, jason.muise@usask.ca

The geochemical controls on the long-term transport of reactive solutes in clay-rich aquitards are difficult to quantify. Two novel approaches, combining centrifuge modeling with ICP-MS, were used to characterize and quantify the retardation of lanthanide and trace metals in one undisturbed clay-rich core sample collected from a well-characterized aquitard located in Southern Saskatchewan, Canada. The core sample was 46.0 mm long, had a surface area of 855 mm2, a porosity of 0.3, and a bulk density of 1.97 g ml-1. Influent groundwater was spiked with lanthanide and trace metals, as well as Cl. A UFA Beckman J6-MI centrifuge with installed seal assembly was used to simulate flow through the clay-rich aquitard sample. The sample was run at 3000 rpm (N factor=876). Infusion pumps provided a flow rate of 1.0 ml hr-1. A total of 144 pore volumes (one pore volume=11.78 ml) were passed through the core sample. The Peclet number for the experiment was calculated to be 187; hence advective-dispersive transport dominated solute transport through the core. Samples of effluent were analyzed for lanthanide and trace metals using ICP-MS and Cl was analyzed using an ion selective electrode. Using the effluent chemical data, Kd values for Cl, V, Cs, Ce, Pr, Nd, Sm, Hf, Tl, and U were calculated to be 0.0, 0.3, 2.1, 3.3, 13.3, 13.7, 14.1, 6.2, 1.0, and <0.1 ml g-1, respectively. At the termination of the transport experiment, the adsorption sites for the lanthanides and trace metals were identified using a Cetac LSX-200+ UV Laser Ablation System coupled with an ICP-MS. The data collected to date and the experimental method employed will provide much-needed retardation data to quantify the long-term transport of reactive metals (including actinides) in aquitards.