CHEMICAL, ISOTOPIC, AND HYDROGEOLOGIC INVESTIGATONS OF AN AGRICULTURALLY IMPACTED AREA, SOUTH CENTRAL MICHIGAN
Geochemical data was collected for 12 sampling events over 22 months, from December 1999-September 2001, for Nottawa Creek surface water, 9 water table observation wells, 4 domestic drift wells, 2 streambed wells, and 8 tile drains. Tile drains are a major contributor of nitrogen and phosphorus to surface water. Despite this, Nottawa Creek nutrient concentrations were consistently low.
Tritium results from the two streambed wells, which are relatively uncontaminated, indicate groundwater discharging into Nottawa Creek is post-bomb water. Values of d15N and d18O from nitrate from most wells and tile drains suggest field applied synthetic fertilizer, composted manure, and liquid manure is transformed or not present. Conversely, wells adjacent to an animal waste lagoon and a compost pile exhibit an animal waste isotopic signature.
Concentrations detected by immunoassay are reported for triazine and chloroacetanilide residues. Triazines are leached vertically via preferential flow and transported to surface water by tile drains. Low or non-detect triazine concentrations in observation wells suggest significant degradation or retardation. Comparatively, chloroacetanilide test results indicate a much greater detection of residue in wells while largely undetected or at low concentrations in tile drains.