IMPLICATIONS OF THE DRIFT SCALE HEATER TEST AT YUCCA MOUNTAIN FOR EPITHERMAL MINERALIZATION
Despite obvious differences from epithermal systems (e.g., the DST is being conducted in an unsaturated system), the trends observed in the isotopic compositions of the water and CO2 have interesting implications for natural systems. In areas below boiling, the isotope ratios of the water are near that of the ambient porewater (d18O about 12). Where significant amounts of vapor condensate occur (above the boiling front above the drift and in fracture zones to the sides of the drift), the d18O values of the water are lower than the pore water, reflecting addition of low-d18O steam condensate. Conversely, in boiling zones the d18O values of the water become progressively higher, representing Rayleigh fractionation of the pore water as it is vaporized. As the temperature approaches boiling, the gas phase becomes dominated by water vapor. The remainder of the gas phase consists of air with elevated CO2 (up to 15%). The source of the CO2 is primarily dissolved inorganic carbon (DIC) in the pore water. As the temperature increases, the d13C values of the CO2 shift from approximate equilibrium with the pore water DIC (-15) to much higher values (>0). Dissolution of calcite in fractures is also a significant source of CO2 in regions with drainage of vapor condensate. Isotopic data from several Mexican epithermal vein systems will be discussed in light of these findings.