SULFUR, OXYGEN AND HYDROGEN ISOTOPE STUDIES OF CONDUIT FRESHWATER SPRING AND MINERAL SPRING FLOW ON THE KARST MITCHELL PLAIN AND THE CRAWFORD UPLAND OF SOUTHERN INDIANA
Sulfur isotopic values d34S (SO4) for springs in the study area range from +1.1 to +22.1 d34S of HS- range from 0.2 to 38.4. The fresh water springs have lighter d34S (SO4) values approximately 10 . The mineral springs are approximately 14 similar to values of the local St. Louis gypsum (14 to 16 ). Heavier d34S (SO4) values (18 to 19 ) in water such as Pluto spring are due to bacterial fractionation. Orangeville rise a major fresh water spring has a low flow d34S (SO4) of approximately +16 and a sulfate concentration of 160 mg/l. The d34S (SO4) and sulfate concentration decreases to +9 and 40 mg/l respectively at high flow. This suggests the mixing of shallow epikarst water and deeper mineral waters.
The ranges of d18O and 2H in the spring waters are -7.0 to -8.0 and 42 and 49 respectively. Except for slight deviations they follow the local meteoric water line. Tritium data previously collected on four of the springs indicate that one is pre-bomb water and the others are a mixture of pre-bomb and recent water.