Paper No. 0
Presentation Time: 8:45 AM
PALEOCLIMATIC INFERENCES FROM THE D/H RATIO OF BULK ORGANIC MATTER IN LAKE SEDIMENTS
We have carried
out multiple isotope measurements on organic matter extracted from a sediment
core from Lake Winnebago in Wisconsin, USA. Based on radiocarbon dates
of the organic fraction, the record spans the past 12k years. The C/N ratio
average around 10 indicating that the sediments are predominantly lacustrine
in origin. Although a lack of correlation between d13C
and d18O values may be taken to rule
out carbonate precipitation via evaporative processes, the d18O
values could not be translated to any meaningful climatic information.
On the other hand the dD values of the organic
fraction, extracted by cycles of HF-HCl digestion of the bulk sediment
could be used to document interesting paleotemperature information for
the region. The dD values ranged from -129
to -142 with the higher values corresponding the previously documented
Mid Holocene Warm between 7k and 4k radiocarbon years. Paleotemperatures
were estimated by converting the dD values of
the organic fraction to the dD values of the
lake water and by implication to that of local precipitation. The
temperature estimates show that MHW was warmer by about 30C,
in agreement with speleothem data from the Midwestern United States (see
figure). Our study shows the usefulness of bulk sediment D/H ratios as
a climate proxy that can compliment compound specific hydrogen isotope
studies.