MAFIC HYALOCLASTITES AND PILLOW BASALTS OF THE BISBEE BASIN, SE AZ: RECORD OF LATE JURASSIC TECTONICS IN THE BORDER RIFT
Pillows and lavas of the suite are presumably mafic (SiO2=50.0-55.6%; MgO=3.6-7.3%) but have interacted with sea water during eruption, resulting in high volatile content (4.4-8.3%) and alkalis (2.8-6.0% Na2O; 1.5-6.3% K2O). Weakly correlated major element compositions suggest that seafloor alteration has changed the concentration of many, if not most, elements in these rocks. However, the immobile elements Ni, Cr, Zr, Nb, Y, and TiO2 form coherent trends. For instance, there is no correlation between MgO and Ni or Cr, although Ni (36-108 ppm) and Cr (68-140 ppm) are positively correlated. Zr, TiO2, Y and Nb (Zr: 125-229 ppm; TiO2: 1.3-2.0%; Nb: 10-30 ppm; Y: 24-33 ppm) are positively correlated with each other. Each of the three complexes contains a range of compositions, suggesting that the vents were fed by magma chambers that were frequently replenished with fresh magma. Fractional crystallization models predict extensive fractionation to produce the range of trace element compositions. Thus, the stratigraphy, lithology, and geochemistry of this basalt complex all support the hypothesis that the lavas were erupted in a submarine rift environment from magma chambers that behaved much like mid-ocean ridge chambers. The Chiricahua pillow basalts comprise one of several examples of Late Jurassic mafic magmatism in the Border rift of northern Mexico and the southwestern US.