GSA Annual Meeting, November 5-8, 2001

Paper No. 0
Presentation Time: 1:30 PM

THE CANDELARIA CU-AU DEPOSIT, III REGION, CHILE: PRODUCT OF LONG-TERM MIXING OF MAGMATIC-HYDROTHERMAL AND EVAPORITE-SOURCED FLUIDS


ULLRICH, Thomas D.1, CLARK, Alan H.1 and KYSER, T. Kurtis2, (1)Department of Geological Sciences and Geological Engineering, Queen's Univ, Kingston, ON K7L 3N6, Canada, (2)Geological Sciences and Geological Engineering, Queen's Univ, Kingston, ON K7L 3N6, ullrich@geoladm.geol.queensu.ca

Andesite-hosted mineralization in the Lower Cretaceous Candelaria deposit (Lat. 27°30'53"S, Long. 70°17'22" W; 470 Mt @ 0.95% Cu, 0.22 g/t Au) was largely associated with Ca-amphibole (40Ar-39Ar plateau: 111.7±0.8 (2ó) Ma), albite, microcline, magnetite and green biotite (112.8±0.7 Ma), followed by subordinate chalcopyrite-epidote-chlorite and, finally, chalcopyrite-hematite-calcite-chlorite stages. The hydrothermal system, hypersaline and CO2-rich throughout, cooled from over 400°C to below 275°C. Ore deposition and Ca-metasomatism, which simultaneously generated Cu-poor andradite-diopside-scapolite “skarn” in the andesitic hanging-wall of the orebody, were preceded at 114.1±0.7 Ma by large-scale and locally intense Fe- and K-metasomatism, generating, respectively, magnetite and brown biotite, a process contemporaneous with ductile deformation along major faults. This barren precursor alteration was itself superimposed on a wider zone of quasi-pervasive albitization of the andesites and, locally, adjacent granitoids. O and S isotopic compositions of ore and alteration minerals predicate progressive changes in fluid chemistry during hydrothermal activity. Thus, d18Ofluid evolved from ca. +7.0‰ for pre-ore K-metasomatism, similar to values for contiguous granitoids (+5.4 to +9.6‰), to ca. –0.2‰ in the late “Olympic Dam-like” stage. d34Sfluid simultaneously increased from “magmatic” values of £+5.7‰ in the earliest Cu(-Mo, Zn, Au, Ag) ore sub-stage to +12.0<x<+20.2‰ during precipitation of late-stage chalcopyrite-hematite and terminal-stage anhydrite. Hydrothermal activity was focused at the W margin of a defunct Valanginian-to-Barremian (ca. 138-119 Ma) back-arc, shallow-marine basin which incorporated evaporites. The isotopic data record a progressive mixing of magmatic-hydrothermal with non-magmatic, plausibly evaporite-sourced waters. Mineralization overlapped temporally with the intrusion of the medium-K calc-alkaline Ojancos Plutonic Complex from 117.2±1.0 to 110.5±1.7 Ma (new 40Ar-39Ar dates), a probable source of ore-metals and juvenile fluids, and also with the uplift of the nearby evaporites.