Paper No. 0
Presentation Time: 9:15 AM
TEMPORAL OVERLAP OF SUPERGENE ALTERATION AND HIGH-SULFIDATION MINERALIZATION IN THE SPENCE PORPHYRY COPPER DEPOSIT, II REGION, CHILE
Hypogene
mineralization in the Spence porphyry Cu (-Mo) deposit (22°47'S; 69°15'W; 400
Mt @ 1.0% Cu), a link in the Central Andean lower Eocene porphyry belt, largely
accompanied intrusion of a NE/SW array of dacite porphyry stocks, articulated
by NW/SE faults within an evolving strike-slip duplex. A-type Cu and
subordinate B-type Cu-Mo veins were emplaced at 57.00 ± 0.69 (2 s) - to - 56.61 ± 0.63 Ma
(laser 40Ar-39Ar plateaus for magmatic biotite in pre-
and late-mineralization stocks); subsequent D-veins introduced mainly pyrite.
13 inverse isochron ages for unambiguously
supergene alunites and natroalunites from leached and chalcocite
enrichment zones range from 44.44 ±
0.54 Ma, the oldest yet recorded for a N Chilean porphyry system, to 27.74 ±
5.42 Ma, a protracted history extended by a
K-Ar date of 20.9 ± 2.2 Ma.
Supergene activity therefore persisted from at least the initiation of
the late Eocene early Oligocene Incaic orogeny, when the deposit was gently
folded, to the major uplift and erosional events of the Aymará tectonic
phase. The intermediate stages of this
long history coincided with the emplacement in the central part of the deposit
of a series of high-sulfidation veins bearing varying proportions of enargite,
tennantite, bornite, covellite, pyrite and alunite. Three hypogene alunites, from sites 46 to 113m below the base of the enrichment blanket,
yield 40Ar-39Ar dates of 33.22 ± 1.86, 33.44 ± 1.09 and
35.57 ± 1.43 Ma. Spence lies 20-25 km W of the Argomedo-Calama strand of the
Incaic Precordilleran (Domeyko) Fault System, but experienced minor Cu
mineralization simultaneously with the initiation of major hypogene activity on that structure at this latitude. This
represents the first clearly-defined example of crossover between the two
Paleogene porphyry Cu belts.