INDIAN OCEAN HYDROTHERMAL MINERAL DEPOSITS: CU-RICH AND EPITHERMAL AU-/AG-ENRICHED OCCURRENCES
The Sonne Field appears to be a typical mid-ocean ridge massive sulfide occurrence with black and white smoker mineralizations; it is now, however, in a state of physical and chemical disintegration, and therefore depleted in anhydrite. The chimney structures were formed by multiple hydrothermal events. Three types of sulfide mineralizations can be distinguished: (1) Cu-rich massive sulfides, (2) pyrite-markasite massive sulfides, both of which originate from the black smoker activity, and (3) sphalerite- and barite-bearing jasper breccia, this latter obviously having been formed at epithermal temperature conditions. In contrast, the Mount Jourdanne deposit shows a much more complex mineralogy. Based on the macroscopic features, the samples can also be subdivided into three groups: (1) tube-like, small massive sulfide chimneys, (2) mound massive sulfides, and (3) clastic ore. All three contain the following minerals: sphalerite, pyrite, markasite, chalcopyrite, silica and barite, and to a lesser degree, galena and cubanite; on fissures and cracks even realgar, boulangerite, and Pb-As-sulfosalts were observed. The latter three mineral phases, together with galena, are quite unusual for massive sulfides in a basaltic environment. The Pb- and As-rich samples also contain surprisingly high concentrations of Au and Ag.
In order to explain these specific mineralization patterns, a very extreme fractionation process must have taken place, possibly in combination with a felsic source rock in the deeper underground. Since elements like Pb, Ag, Zn, and As like to form highly soluble chloride and chloro- complexes, we suggest that phase separation and the respective development of a brine has caused this unusual metal assemblage . Similar genetic conditions can be completely excluded for the Sonne Field massive sulfides.