THE COLD-TRAP PROCESS AND ITS EFFECT ON MOISTURE DISTRIBUTION AND CHEMISTRY OF WATER IN DRIFTS
The cold-trap process involves evaporation from warm areas, movement of vapor driven by thermal gradients, and condensation on cool or hygroscopic surfaces. Predicting moisture movement associated with the cold trap process is complex. Natural convection, when acting in concert with thermal radiation, conduction, and latent heat transfer, is poorly understood. In regard to chemistry, condensate associated with the cold-trap process is essentially pure water with a pH dependent on the atmospheric CO2(g) content. However, mixing of waters from different sources (e.g., condensation and seepage), each of which may have contacted and reacted with different materials (substrate, residues, or dust), makes it difficult to predict chemical compositions of the water in drifts.
The cold trap process was evaluated in a scaled laboratory model of a heated drift using thermocouples, relative humidity probes, and anemometers to measure environmental conditions. Preliminary results from the laboratory test support results from an analytical solution of air flow patterns and condensation rate. A computational fluid dynamics code and a two-phase porous media code were calibrated to expand predictive capabilities beyond the results measured in the laboratory experiment. This presentation will summarize existing published work on the cold trap process, present preliminary results from scaled laboratory experiments and corresponding modeling, and highlight the large data gap that exists for building confidence in a thermal-hydrologic-chemical modeling approach.
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