2002 Denver Annual Meeting (October 27-30, 2002)

Paper No. 13
Presentation Time: 1:30 PM-5:30 PM

GROUND WATER AGE VARIABILITY WITHIN A GLACIAL AQUIFER BENEATH A THICK UNSATURATED ZONE


STOTLER, Randy L.1, FRAPE, Shaun K.2, SUDICKY, Edward A.1, DRIMMIE, Robert J.2, PLUMMER, L. Niel3, BUSENBERG, Eurybiades4, POREDA, Robert J.5 and HARVEY, F. Edwin6, (1)Earth Sciences, Univ of Waterloo, Waterloo, ON N2L 3G1, Canada, (2)Earth Sciences, University of Waterloo, Waterloo, ON N2L 3G1, Canada, (3)U.S. Geol Survey, Reston, VA 20192, (4)US Geological Survey, 432 National Ctr, Reston, VA 20192, (5)Earth and Env. Sci, Univ Rochester, Rochester, NY 14627-9000, (6)School of Natural Resource Sciences & Conservation and Survey Division, UNL, Lincoln, NE 68588-0517, rlstotle@scimail.uwaterloo.ca

The Waterloo Moraine Aquifer Complex supplies 56% of the drinking water to the Region of Waterloo. Within the last 12 years, a concerted effort has been made to better understand the flow system of this heterogeneous aquifer system. The aquifer complex consists of alternating aquifers and aquitards, reflecting the interlobate nature of the moraine. It has been recognized that the aquitards are laterally discontinuous; “windows” in the aquitards may allow hydraulic connectivity between the aquifers. In 1993-1994, a geochemical and isotopic (2H, 18O) survey of the aquifer was completed, and two transects were sampled for 3H, CFC and 3H/3He age dates. Several large nitrate plumes were discovered and mapped under the largely agricultural moraine surface. Regional flow models incorporating inverse particle tracking were also constructed to determine wellhead vulnerability. The flow models have not yet been calibrated to the age data.

Prior to using age data to calibrate the regional flow model, it is important to answer the question “How accurate are the age data in the heterogeneous aquifer?” A second round of geochemical, isotopic and age data were collected, this time utilizing 3H, 3H/3He and SF6 environmental tracers. Nitrate concentrations have generally increased over portions of the aquifer that are upgradient from the production wells, although dissolved gas data suggests denitrification may be occurring. The geochemical data has been combined with dissolved gas and the age tracers to evaluate mixing and ground water flow patterns along the two transects.