IMPLICATIONS OF ANOMALOUS D33S FOR EVOLUTION OF ATMOSPHERIC OXYGEN, CONTINENTAL WEATHERING, AND PALEOPROTEROZOIC GLACIATIONS
Glacial diamictites from the Huronian Supergroup of southern Ontario, Canada and stratigraphically equivalent units on continents other than North America suggest that such a global glaciation may have existed between ~2.4 and ~2.2 Ga. We report the multiple sulfur isotopic composition (32S, 33S, 34S) of Cr-reducible sulfur (CRS) from detailed sampling of a drill core through the earliest Huronian glacial interval made up of the Ramsay Lake diamictite, the underlying McKim Formation, and overlying Pecors Formation. Through the drill core, D33S values of CRS range between 0.22 to ~ 0 and vary systematically with depth. Within 6 meters of the contact of the McKim Formation and the overlying diamictite, D33S decreases from 0.22 to 0.16 , immediately above the diamictite to ~5 meters into the overlying Pecors Formation, D33S is within analytical error of 0 , and from ~ 6 - 15 meters above the diamictite D33S increases uniformly from 0 to 0.1 . The small measured range of the D33S values from the McKim and Pecors Formations is consistent with the observed contraction in the mass-independent record of Earths early sulfur cycle between ~ 2.5 to 2.0 Ga. The systematic variation of D33S with depth, however, implies a significant relationship between atmospheric oxygen levels and the weathering rates of continental sulfides, sulfates, and organic sulfur, and the global Paleoproterozoic glaciation.