ISOTOPIC HETEROGENEITY AND CRYSTAL ISOTOPE STRATIGRAPHY OF FLOOD BASALT LAVAS: THE COLUMBIA RIVER BASALT GROUP
We have used laser ablation and microdrill sampling techniques in conjunction with both high resolution and multicollector ICP-MS to analyze trace element concentrations and Sr isotope ratios from individual growth layers within plagioclase phenocrysts and from the associated groundmass within flows from each major CRBG formation. 87Sr/86Sr variations within individual phenocrysts and between phenocrysts and host matrix offer unequivocal evidence for open-system processes during phenocryst growth, and it is clear that CRBG magmas were assembled, at least in part, in crustal magma chambers. By applying one-dimensional diffusion modeling to observed 87Sr/86Sr zoning and crystal/groundmass gradients constrain phenocryst residence times, the timescale of crustal-level petrogenetic events can be constrained. Residence times for phenocrysts in their final host liquid may be as little as a few years prior to quenching.
Isotopic heterogeneity in individual CRBG flows may result from mixing between magmas from isotopically distinct mantle reservoirs and/or crustal contamination during and after phenocryst growth in crustal magma chambers. The very short timescales implied by crystal-matrix isotopic disequilibrium most likely result from syn-eruptive mixing of magmas derived from different locations within a spatially heterogeneous magma chamber.