2004 Denver Annual Meeting (November 710, 2004)
Paper No. 82-7
Presentation Time: 9:35 AM-9:55 AM

SURFACE OXIDATION STATES AND THE ARCHEAN/PROTEROZOIC TRANSITION

MOJZSIS, Stephen J. and PAPINEAU, Dominic, Department of Geological Sciences, Univ of Colorado, UCB 399, 2200 Colorado Avenue, Boulder, CO 80309-0399, mojzsis@colorado.edu

Which determined the surface oxidation state of the present Earth: mantle changes, tectonics, biological innovation, or all three? Current thought ascribes the evolution of microbial diversity and its modulation of global biogeochemical cycles as being intimately linked with changes in the surface oxidation state and tectonic regime of the planet over geologic time. However, exploring for a chemical record of these changes is fraught with difficulty due to the ephemeral nature of the atmosphere, problems in interpreting chemical or morphological remnants of life and modifications to the record by metamorphic overprinting.

New insights can be gained regarding the rate function of p O2 increases in the Precambrian by using a combined approach that couples mass-independently fractioned (MIF) sulfur isotopic signals expressed as Δ33S or the deviation from a mass-dependent fractionation line for the 3-isotope system (34S/32S vs. 33S/32S) in sulfides, with the nitrogen isotopic record (expressed as d15NAIR) of kerogens and a growing body of data for ammoniated phyllosilicates. These data are derived from a wide variety of Archean, Proterozoic and Phanerozoic sediments. It has been proposed that changes in mantle oxidation state could have played a part in delaying the rise of atmospheric oxygen until ca. 2.32.4 Ga. Secular changes in sedimentation style in concert with the stabilization of the continents and a relatively "late"(?) rise of cyanobacteria coincided with the progressive and irreversible oxidation of the surface zone in the Paleoproterozoic. This view is supported by existing sulfur and nitrogen data, observations for no significant changes in mantle f O2 over geologic time, geochemical biomarker studies and molecular phylogenetic reconstructions.

2004 Denver Annual Meeting (November 710, 2004)
General Information for this Meeting
Session No. 82
1500 to 2500 Ma: A Period of Changing Mantle Regimes in Earth History?
Colorado Convention Center: 708/710/712
8:00 AM-12:00 PM, Monday, 8 November 2004

Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 206

© Copyright 2004 The Geological Society of America (GSA), all rights reserved. Permission is hereby granted to the author(s) of this abstract to reproduce and distribute it freely, for noncommercial purposes. Permission is hereby granted to any individual scientist to download a single copy of this electronic file and reproduce up to 20 paper copies for noncommercial purposes advancing science and education, including classroom use, providing all reproductions include the complete content shown here, including the author information. All other forms of reproduction and/or transmittal are prohibited without written permission from GSA Copyright Permissions.