COPPER MINERALIZATION AT KENNECOTT, ALASKA: A FLUID MIXING EVENT CONTROLLED BY HIGH-ANGLE STRUCTURES
Copper, mobilized from the underlying Triassic Nikolai Greenstone by a warm (~200ºC), oxic fluid produced by dehydration reactions during prehnite-pumpellyite grade metamorphism that also carried sulfur, precipitated as both native copper and copper sulfides in the Nikolai (δ34S ~0). These copper- and sulfur-bearing fluids from the greenstone mixed with anoxic, basinal, fluids containing reduced sulfur that originated within the Triassic Chitistone Limestone. Mixing of the two fluids occurred in the lowest 100 m of the Chitistone Limestone in favorable structural traps. The fluids, localized in a circulation cell established between the limestone and greenstone, reacted with original sedimentary pyrite and precipitated extremely depleted copper sulfides (δ34S as low as -36.7) in the uppermost Nikolai Greenstone. The bulk of the hypogene mineralization occurred at ~90ºC with the precipitation of massive orthorhombic chalcocite-djurleite in the Chitistone Limestone.
The mineralization event, including the development of high-angle structural traps and the mixing of the two fluids, occurred during the waning stages of the late Jurassic to Cretaceous orogeny coincident with the accretion of the Wrangellia terrane (~110 Ma).