DEVELOPING THE PALEOENVIRONMENTAL RECORD FROM BIG BONE LICK, KY: MINERALOGICAL, GEOCHEMICAL, AND ISOTOPIC CONSTRAINTS
A more complete understanding of paleoenvironmental conditions is being developed using clay mineralogy, bulk geochemical (metals; %Corg, %N), and stable isotopic (d 13C, d 15N of bulk organic matter) techniques. Preliminary results from x-ray diffraction studies indicate a predominance of expandable clays, including mixed-layer assemblages, together with illite and possibly vermiculite. With the exception of the uppermost soil zone, the sediments show a range in %N and %Corg from 0.04%0.11% and 0.2%1.0%, respectively, with higher concentrations within the lower blue-gray clay. Preliminary C/N and d13Corg results indicate distinct differences in either the type or level of degradation of organic matter preserved in the sediments. Future work will focus on further defining the paleoenvironmental significance of down-core changes in the organic signatures. The above results, coupled with studies of bulk-core analysis (natural gamma, magnetic susceptibility, bulk density), palynology, and sediment grain analysis will provide a more complete view of glacial-age paleoenvironmental conditions within a small catchment proximal to an important hydrological and sedimentological transport pathway.