DEVONIAN K-BENTONITES AND TUFFS: A RECORD OF CALEDONIAN MAGMATISM FROM THE APPALACHIAN FORELAND BASIN (EASTERN U.S.)
Approximately 100 K-bentonites and tuffs are known from the Devonian of the Appalachian foreland basin. These include clusters of several closely-spaced beds, and additional beds scattered through the succession. Some K-bentonites occur widely across the eastern U.S. (e.g., some beds of the Tioga and Belpre clusters and the Center Hill K-bentonite); some are restricted to portions of the Appalachian Basin (e.g., Tioga Middle Coarse Zone); others are only regionally to locally recognized. The highest concentration of K-bentonites and tuffs occurs in the Eifelian Stage (>40 beds). The known distribution of Devonian K-bentonites and tuffs through time, by stage, is as follows (K-bentonites dates from Tucker et al., 1998, and Roden et al. 1990; simplified stage boundary ages from Kaufmann 2006).
Lochkovian Stage (lower Lower Devonian, ca. 418-412 Ma): Bald Hill K-bentonites, up to 15 beds, 417.6 +/-1.0 Ma. Pragian Stage (middle Lower Devonian, 412-409 Ma): No K-bentonites reported. Emsian Stage (upper Lower Devonian, ca. 409-392 Ma): Sprout Brook K-bentonites, up to 15 beds, 408.3 +/-1.9 Ma. Eifelian Stage (lower Middle Devonian, ca. 392-388 Ma): Tioga Middle Coarse Zone, up to 32 beds, 391.4+/-1.8 Ma; Tioga A-G K-bentonites, up to 11 beds, 390 +/-0.5 Ma; and additional beds scattered throughout the Eifelian. Givetian Stage (upper Middle Devonian, ca. 388-384 Ma): Three K-bentonites reported; several undocumented clay layers scattered through the succession may be K-bentonites. Frasnian Stage (lower Upper Devonian, ca. 384-376 Ma): Belpre K-bentonites, up to 6 beds, 381.1 +/-1.3 Ma; Center Hill K-bentonite, close to 376 Ma; and a few additional beds. Famennian Stage (upper Upper Devonian, ca. 376-361 Ma): One K-bentonite reported, in low Famennian strata (close to 376 Ma).