VOLCANIC GEOLOGY OF THE CERRO CASTELLAN AREA, BIG BEND NATIONAL PARK, TEXAS
Mafic units include basalt, hawaiite, mugearite, shoshonite and latite. No Daly Gap is present, but a compositional gap of ~7 wt. % SiO2 exists between trachyte and peralkaline rhyolite. Magmatic enclaves of trachyte, however, are common in some silicic domes. These suggest that trachyte and rhyolite are co-genetic. Major and trace element modeling has demonstrated that variation within peralkaline rhyolite could be explained by reasonable amounts of crystal fractionation of observed phenocrysts.
Sample/mantle ratio plots for basalts show the convex upward plot with a gentle slant downwards towards Y and Yb characteristic of Ocean Island Basalt. Evolved units (trachyte and peralkaline rhyolite) show expected increases in incompatible elements, with negative anomalies developed for elements expected to be relatively depleted by fractional crystallization of observed phenocrysts (Ti, Eu, P, Sr, Ba). Several samples show, in addition, a slight negative Nb anomaly, which may be attributed to assimilation of crustal material with such geochemical signature.
All Cerro Castellan rocks erupted within the span ~46-29 Ma are alkalic; mafic units show no detectable geochemical change during this period that may be associated with a hypothesized tectonic shift from regional compression to Basin and Range extension. Furthermore, the appearance of local peralkaline rhyolite at ~29 Ma has no regional significance, as similar peralkaline rhyolite was erupted much earlier elsewhere in west Texas.