GEOCHEMISTRY AND HYDRAULIC FRAMEWORK OF AN ISOLATED HOT SPRING, TECOPA BASIN, CALIFORNIA
Seven springs in the Tecopa Hot Springs area and two other nearby springs were sampled in May 2006 for major, minor, and trace element chemistry, and oxygen and hydrogen stable isotopes. In addition, thermal water from Grimshaw spring (Tecopa Hot Springs) and ambient-temperature waters from Shoshone and Amargosa Borax Works springs were sampled for noble gas and Sr isotope compositions. The water chemistry compositions at Tecopa Hot Springs generally fall into three categories: (1) pH-neutral to slightly alkaline, Na+Ca+Mg+SO4+HCO3 water with moderate dissolved solids, (2) slightly alkaline, Na+Cl+SO4+HCO3 thermal water with moderate to high dissolved solids, and (3) alkaline Na+Cl+SO4+HCO3 waters with high dissolved solids. Whereas the first two categories fall into regionally defined water compositions (Larsen et al, 2001), category 3 waters appear to be partially evaporated runoff from the thermal springs. Noble gas-based recharge temperatures, corrected for excess air, range from 15 to 25 degrees Celsius, suggesting external thermal input. However, only Grimshaw spring shows a significant mantle or crustal gas component. R/Ra values for Grimshaw, Shoshone, and Amargosa Borax Works are 0.08, 0.10, and 0.13, respectively. Given these values, the waters are interpreted to have accumulated 4He along long flow paths with Grimshaw waters receiving the greatest crustal flux of heat, 4He and other noble gases. Geologic mapping suggests that spring discharge is related to ground-water flow from the northeast, with water moving along a subdominant northeast-oriented joint system.