2009 Portland GSA Annual Meeting (18-21 October 2009)

Paper No. 7
Presentation Time: 9:00 AM-6:00 PM

SEDIMENT PHASE ASSOCIATIONS OF TUNGSTEN IN THE ALLUVIAL AQUIFERS, FALLON, NEVADA


CUTLER, Nicole K., Hydrological Sciences, University of Nevada, Reno, MS 176, Reno, NV 89557, STILLINGS, Lisa L., USGS, University of Nevada, Reno, MS 176, Reno, NV 89557 and MCCORMACK, John K., Department of Geological Sciences and Engineering, University of Nevada, Reno, MS 172, Reno, NV 89557, cutlern@unr.nevada.edu

Investigations into possible environmental causes of a childhood leukemia cluster in Fallon, Nevada, revealed high concentrations of tungsten (W) in airborne dust, lichens, and in groundwater of the local alluvial aquifers. While the connection between W and cancer remains under investigation, these observations have underscored our lack of knowledge of the W geochemical cycle in the environment. Natural sources of W in the Fallon area include weathering products of scheelite (CaWO4) from W occurrences in the surrounding mountain ranges and W from geothermal waters. The purpose of this research is to determine the concentration, spatial variation, and phase association of W in the aquifer sediments.

Aquifer sediments, in the surrounding areas of Fallon, NV, were collected using a split spoon drill core, processed under a nitrogen environment, and characterized by total bulk chemistry (ICP-AES/MS), SEM/XRD, and selective extractions. Sediments consisted of coarse sands, silts, and black clays, composed of augite, biotite, K-feldspars, plagioclase, quartz and amorphous Fe coatings. The sands contain hematite and illmenite, whereas the finer grained sediment consistently contained pyrite, illite and kaolinite. Concentration of W in bulk sediments ranged from 1.3 – 7.9 mg/kg, and is a function of grain size. The average concentration of W in the sands (2.7 mg/kg) was significantly different from the concentration in silts and clays (5.3 mg/kg) as determined by a t-test at P=0.009. Approximately 90% of the extracted W partitioned into three sediment phases: non-crystalline iron oxides, crystalline iron oxides, (collectively referred to as FeOx), and organic matter (OM). Extracted Fe and bulk organic C (Org C) concentrations were greater in the silts and clays (FeOx = 8.1%; Org C = 3.4%), than in the sands (FeOx = 5.8%; Org C = 0.19%), with a significant difference in mean values between the two grain sizes (P=<0.001). Concentration of W in sediments sampled at the depth of the well screen correlated (R2 = 0.94) with W concentration in groundwater (12.8 – 661 µg/l W) collected adjacent to sediment cores. From this data we conclude the concentration of W in sediments is controlled by the presence of FeOx and OM phases, and correlates with W concentrations in the groundwater.