INTERNAL PHOSPHORUS CYCLING IN UTAH LAKE: DETERMINING POTENTIAL FOR FUTURE EUTROPHICATION USING A CONCEPTUAL MODEL
Since the lake is a net sink for P, we investigated likely pathways for P sequestration. We characterized sediment samples from the lake by X-Ray Diffraction (XRD), selective dissolution, and P-adsorption experiments. Six sediment samples were analyzed using XRD and RockJock (USGS) analysis software. Surface areas of two samples were determined. A selective dissolution sequence quantified fractions of P bound by the following sorption modes: dissolved, ion-exchange, Fe and Al sorbed, apatite-bound, Ca-bound and organic-bound P. Ca-bound P was determined to be the dominant fraction.
We constructed a STELLA model based on inferences from experimental results and assumptions about the system. The model included modules for P-coprecipitation with calcite, aqueous P flux, P-sorption onto sediments, and sediment sequestration. Water fluxes and P concentrations were assumed to be at steady state under present conditions, consistent with records over the past few decades. We assumed that P precipitated with calcite would be permanently sequestered, due to the lake being supersaturated with respect to CaCO3. We also assumed a sedimentation rate of 1 mm/yr, and the top 1 ft. of sediment to be available for adsorption reactions.
Responses of P concentration to changing input levels from wastewater treatment plants were then modeled. The model reestablished steady-state conditions within 2.5 to 4 years.
Future modifications of the model will include optimization of predicted P coprecipitation rates based on electron microprobe data, and sequestration of P in refractory organic matter.