ORE MINERALOGY OF THE WORLD-CLASS GAMSBERG ZINC SULFIDE DEPOSIT, SOUTH AFRICA
A detailed mineralogical and mineral chemical assessment of the Gamsberg deposit has resulted in the definition of four sphalerite populations (i.e. Fe-rich, Mn-poor, Mn-rich, and Zn-rich). Petrographic analyses indicate that the Fe-rich population, which consists of very fine-grained (10’s micron) crystals disseminated throughout the host rock, represent the composition of the original sulfide mass. The Mn-poor and -rich (i.e. Mn-enriched) populations comprise massive, coarsely crystalline, overgrowths and annealed crystals with minute (micron-sized) inclusions of albandite. Combined, these attributes suggest that the Mn-enriched populations represent the composition of the sulfide mass after metasomatic alteration during peak metamorphism. Morphologically, the Zn-rich population is characterized by anhedral to subhedral, fine- to coarse-grained, porous to void-filling crystals commonly intergrown with microscopic phyllosilicates, suggesting growth under retrograde metamorphic conditions.
The apparent mixing line observed between the Mn- and Zn-rich populations, indicates the introduction of a secondary fluid that interacted with the pre-existing Mn-rich population, resulting in the precipitation of the secondary Zn-rich population, which displays a high degree of scatter on a bivariant plot of Zn versus Mn, a feature common to hydrothermally altered minerals.