PRELIMINARY GEOCHEMISTRY OF THE BOSSIER-HAYNESVILLE FORMATION FROM EAST TEXAS BASIN, EAST TEXAS AND LOUISIANA
Ten cores from eight counties in Texas and two parishes in Louisiana have been studied for their geochemistry. Each core was scanned at a 1-foot interval using a Bruker handheld x-ray fluorescence (XRF) instrument, providing rapid, quantitative analysis of the following elemental concentrations: Mg, Al, S, Si, P, K, Ti, Ca, Mn, Fe, Mo, Cr, Ni, Cu, Zn, Th, Rb, U, Sr, Zr, and V. In addition to metal data, preliminary interpretations for total inorganic carbon (TIC), total organic carbon (TOC), total nitrogen (%N), and bulk rock TOC and N isotopic composition of core samples reveal distinct differences between the Bossier and Haynesville formations. Results from previous geochemical studies suggest that the siliciclastic-dominated Bossier formation has less TOC than the underlying Haynesville formation. Furthermore, the Haynesville is much more carbonate-rich (calcite) than the overlying Bossier. An upwardly increasing trend in Si/Al in some cores suggests increasing detrital quartz influx. A linear relationship between Fe and Al suggest that iron is primarily in clay mineral phases in the Haynesville. Mild enrichments in Mo concentrations and Cr/V ratios reveal periods of anoxic conditions. Peaks of redox-sensitive elements like Mo, Fe and V indicate periodically anoxic conditions during deposition.