RECALIBRATING THE LOWER CRETACEOUS TIME SCALE WITH U-PB ZIRCON AGES FROM THE GREAT VALLEY GROUP
The paucity of high-precision radiometric ages from the Lower Cretaceous was highlighted in the 2004 publication of the Geologic Time Scale, and high stage boundary age uncertainties reflected the challenges inherent in the construction of a time scale from so few tie points. However, U-Pb geochronology of volcanic horizons from the Great Valley Group, a group of rocks with well-documented macrofossil and calcareous nannofossil biostratigraphy, can supply much needed radiometric ages for the Lower Cretaceous Time Scale.
Four new zircon U-Pb ages from the Great Valley Group require adjustments to parts of the Lower Cretaceous Time Scale: a Lower Aptian concordia age of 124.07 ± 0.13 Ma is in good agreement with the Geologic Time Scale 2008 Barremian-Aptian boundary age of 125.0 Ma, but Upper Berriasian (138.46 ± 0.15 Ma) and two Lower Valanginian ages (137.63 ± 0.14 Ma, 133.66 ± 0.14 Ma) shift the Berriasian-Valanginian and Valanginian-Hauterivian boundaries to approximately 138 Ma and 133 Ma, respectively. These new boundary ages lengthen the duration of the Berriasian from 5.3 m.y. to 7.5 m.y. and shorten the duration of the Valanginian from 6.3 m.y. to 5 m.y. These results 1) adjust the timing of the Valanginian δ13C positive excursion so that it is synchronous with the main pulse of the Paraná-Etendeka flood basalt volcanism, 2) require a faster seafloor spreading rate during the Valanginian than previously assumed, and 3) suggest a sharper calcareous nannofossil species diversity peak during the Hauterivian.