GEOCHEMICAL ANALYSIS OF A GLACIAL LAKE BENSON VARVE SEQUENCE, WEST-CENTRAL MINNESOTA
Fifteen samples were obtained from an outcrop of consecutive varves near the center of former Glacial Lake Benson (21 km southwest of Benson on Cty Rd 11; UTM 287,900 mE, 5,003,100 mN, Zone 15). A bulk sample of one summer and winter layer was collected for each varve. Varve couplets were 7 to 13 cm thick. Sediment was dry sieved to obtain the silt and clay fraction for major and trace element analysis by x-ray fluorescence (XRF).
Bulk geochemistry within the varved succession is relatively homogeneous, although there is a distinct geochemical partitioning between the bottom and the top of the succession. In particular, large ion lithophile (LIL) elements such as Ba, La and Rb are depleted at the base of the section. Depletion of these mobile LIL elements may indicate selective removal of elements by hydrologic scavenging associated with groundwater movement. XRF results were also compared to regional till geochemistry in the Glacial Lake Benson area, as analyzed by the Minnesota Geological Survey using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) (Thorleifson et al., 2007). Lake Benson sediments are significantly enriched in Cu, Zn, Nb, Zr and Y relative to the till. This geochemical enrichment, particularly in nonmobile elements such as Zr, suggests that Lake Benson sediments might have been derived from a different source than the surficial Des Moines Lobe till.
Research for this study was funded by a grant to Cotter from the NSF-R.E.U. Program (NSF-EAR 0640575).