CALL FOR PROPOSALS:

ORGANIZERS

  • Harvey Thorleifson, Chair
    Minnesota Geological Survey
  • Carrie Jennings, Vice Chair
    Minnesota Geological Survey
  • David Bush, Technical Program Chair
    University of West Georgia
  • Jim Miller, Field Trip Chair
    University of Minnesota Duluth
  • Curtis M. Hudak, Sponsorship Chair
    Foth Infrastructure & Environment, LLC

 

Paper No. 7
Presentation Time: 10:30 AM

DETERMINATION OF SWELLING RATES OF NAu-1 QUASI-CRYSTALS DURING CATION EXCHANGE USING ATOMIC FORCE MICROSCOPY


MATTEI, Michael, HEIST, Christopher A. and MCGUIRE, Molly M., Department of Chemistry, Bucknell University, Lewisburg, PA 17837, mm083@bucknell.edu

In situ observations of the swelling properties of the nontronite clay NAu-1 were carried out via intermittent contact Atomic Force Microscopy (AFM). Using a fluid cell, a sodium saturated sample of NAu-1 was flushed with ultra pure water, allowing osmotic swelling to occur. The system was flushed with 0.5 M KCl solution and changes in swelling were observed in 30- second intervals in real time. Due to the difference in the hydration energy of K+ as compared to Na+, an overall decrease in swelling was observed. However, changes in the d-spacing between different layers within a quasi-crystal were observed to vary from layer to layer, suggesting that mechanical forces also play a role in swelling. With this data, the swelling rates of individual layers can be directly calculated, allowing for a better understanding of the variables that govern the swelling process.
Meeting Home page GSA Home Page