MINERALOGY AND GEOCHEMISTRY OF HAKUREI SULFIDE DEPOSIT, BAYONNAISE KNOLL CALDERA, IZU-BONIN ARC
The Hakurei deposit consists of upper massive sulfide zone of ~1 m thick from seafloor, middle altered dacitic volcanic rocks with disseminated sulfide of ~1.5 m thick, and bottom anhydrite zone of >1.5 m thick. Sulfide minerals observed in upper and middle zones are dominated by sphalerite and lesser amounts of pyrite, chalcopyrite, tennantite, galena, enargite and covellite are accompanied. Grain size of sphalerite in upper massive sulfide zone is fine, whether sphalerite of middle zone is coarser in size with euhedral crystal morphology showing color zoning. Chalcopyrite and/or tennantite disease texture is common in sphalerite. Anhydrite occurs in dacitic tuff, or it occurs as massive crystal that accompanies small amount of sulfides.
Homogenization temperature and salinity of fluid inclusion hosted in sphalerite and anhydrite was examined. Homogenization temperatures vary between 100° and 300°C, and they generally increases with depth from seafloor. Salinities of fluid inclusion are in the range of 1 to 12 wt. % eq. NaCl,. Data of microthermometry for anhydrite occurs in tuff and massive anhydrite are remarkably different. Former has high homogenization temperature and high salinity, while latter has variable homogenization temperatures with low salinity. The d34S values for sulfide minerals fall in narrow range between +3.1 and +5.2 per mil, while those of anhydrite fall between +21.3 and +21.8 per mil, slightly heavier values than that of seawater.