MINERALOGY AND FLUID INCLUSIONS' ANALYSIS IN ZN-PB- BA-SR BOU DAHAR MINING DISTRICT, MOROCCAN HIGH ATLAS
The mineralization, enclosed mainly in Lower and Middle Liassic limestone, is post Jurassic. It occurs mainly along E-W faults. These faults were created during tensional-Jurassic phase then remobilized during compressive post-cretaceous-mineralizing phase. The paragenetic sequence determined by petrographic studies at different ore deposits is listed as follow: quartz-calcite-pyrite-melnicovite-sphalerite-galena-barite-fluorite-celestite.
The analysis of fluid inclusions carried on sphalerite, barite, and celestite reveals a cooling-dilution phenomenon as the cause of the precipitation of the mineralization. This cooling-dilution effect is due to the mixing between a descending cooler and diluted superficial fluid and an ascending, hotter and higher-salinity fluid (brines). This cooling-dilution results in the precipitation of the first stage of mineralization, represented by the sulfides (sphalerite, galena), from fluid F1 (Homogenization Temperature = 165 oC, Salinity = 25 eq. Wt% NaCl). With time, the mixing ratio (descending cool fluid/ hot brine) increases and the dilution and cooling of the ascending brines by the superficial fluid continues and becomes more pronounced. This mixing results in the precipitation of barite from a rare fluid F2a (Homogenization Temperature= 125 o C, Salinity = 22 eq. Wt% NaCl) and a cooler dominant fluid F2b (Homogenization temperature ≤ 50 o C, Salinity = 14 to 19 eq. Wt% NaCl). At the final stage, the descending cooler fluid becomes dominant in the mixing ratio, leading to a very cool and diluter fluid F3 (Homogenization Temperature ≤ 50 o C, Salinity = 5.5 eq. Wt% NaCl) from which Celestine precipitates.