HYDROGEOLOGIC FRAMEWORK OF SPRINGS IN THE LOWER CANYONS OF THE RIO GRANDE, RIO GRANDE WILD AND SCENIC RIVER, TEXAS
Major element variations reveal two groups of springs: one set with an average of 533 mg/L TDS is classified as a no dominant ion (NDI) water and a second with an average of 282 mg/L TDS that is classified as Ca-HCO3 type water. The same two hydrogeochemical facies appear when the waters are classified using isotopic analysis of hydrogen and oxygen. With respect to the NDI waters, the Ca-HCO3 are enriched with deuterium and oxygen-18. GIS analysis of the water chemistry reveals that the NDI waters are located south and west of a major northwest trending structure represented by the Bullis Fold and the Ca-HCO3 waters are located north and east of this structure. Geochemical analysis of ground water reveals a similar patter with NDI water originating from wells southwest of the Bullis Fold and Ca-HCO3 water found in wells northeast of the fold. Variations in the NDI waters could be the result of a longer residence time and possible interaction with Paleozoic sedimentary rocks in the Marathon Basin, located ~30 km to the northwest, beyond the mapped extent of the ET. Potentiometric maps generated of the study area reveal a southeast flow path and suggest potential communication with the Marathon aquifer. Alternatively, the Ca-HCO3 waters may be associated with recent meteoric recharge directly into the ET.