GEOCHEMICAL CHARACTERIZATION OF VEIN-HOSTED GOLD MINERALIZATION IN THE MONEY KNOB DEPOSIT, LIVENGOOD, ALASKA
Previous work has shown that the gold is strongly correlated with the concentration of two sulfides in particular: arsenopyrite (asp) and stibnite (stib). This study sampled several sets of veins containing asp and/or stib, which were designated to one of three categories: qtz-asp, quartz-stib, and quartz-asp-stib. To test the statistical relationship of these vein categories to gold grade, Pearson’s correlation coefficient was calculated for each using ICPMS elemental analyses. Results for each category were as follows: qtz-asp=0.77, qtz-stib=0.55, qtz-asp-stib (using Sb)=0.65, qtz-asp-stib (using As)=0.76. These results indicate that gold is most strongly associated with asp, but is also associated with the presence of stib.
Additionally, sulfur isotope analyses were used to explore the geochemical character of the vein sets. Using sphalerite-pyrite and sphalerite-stibnite pairs, sulfur isotope ratios gave preliminary vein equilibrium temperatures which ranged from 244 to 307°C. Preliminary mean δ34S values for qtz-asp and qtz-asp-stib were -4.51 and -5.15, respectively. These temperatures and isotopic ratios are consistent with other intrusion-related gold veins.