Paper No. 8
Presentation Time: 3:05 PM


KU, Timothy C.W., Earth & Environmental Sciences, Wesleyan Univ, 265 Church Street, 455 Science Tower, Middletown, CT 06459, SHACKLETON, Sarah, Earth and Environmental Sciences, Wesleyan University, 265 Church Street, 455 Science Tower, Middletown, CT 06459, MARTINI, Anna M., Geology Department, Amherst College, 11 Barrett Hill Road, Amherst, MA 01002, HAYNES, Laura L., Geology, Columbia University, 110 Morningside dr, Apt. 8, New York, NY 10027, GAFFEY, Robert, Department of Geology, Amherst College, Amherst, MA 01002 and DONOVAN, Alyssa, Geology, Amherst College, Amherst College, Keefe Campus Center AC133, Amherst, MA 01002,

Carbonate and organic carbon isotope measurements of lacustrine sediments yield excellent paleoenvironmental records provided that the processes influencing sediment d13C values are well understood. While lake sedimentary carbon isotope records are commonly interpreted in terms of allochthonous inputs and water column processes, relatively few studies have examined the effects of early diagenetic processes such as methanogenesis or carbonate mineral recrystallization on sedimentary d13C values. Here, we present lake water, pore water, and sediment chemistry from Lough Carra, a shallow marl lake in western Ireland to 1) evaluate the effect of early diagenesis on lacustrine sedimentary d13C records and 2) document the paleoenvironmental history of Lough Carra. In July 2012, four ~1-meter cores and one 8-meter core were collected from Lough Carra. Overlying lake water and pore water chemistries (pH, T, Ca2+, DIC, d13CDIC, CH4, d13CCH4) indicate rapid groundwater or spring inputs to various basins within the lake. In pore waters significant benthic methane production creates supersaturation with respect to calcite and high d13CDIC values, up to +10‰. In some short cores, age constraints (210Pb, 137Cs, Hg) and sediment chemistries show a decrease in d13COrgC and d13CCaCO3 and an increase in D13CCaCO3-OrgC of several per mil since approximately the late 1800s. The 8-meter core contains laminated marl sediments from ~1.5 – 8 m depth and the d13C data is divided into two basic zones. From 8 to 2.2 m sediment depth, d13COrgC and d13CCaCO3 values slightly increase while D13CCaCO3-OrgC is largely invariant. From 2.2 to 0 m depth, d13COrgC and d13CCaCO3 values decrease rapidly and D13CCaCO3-OrgC is variable. Pore water d13CDIC mass balance models constrain possible DIC carbon sources and the potential shift of bulk carbonate d13C due to precipitation of high d13C calcite after deposition. Along with diagenetic effects, the Lough Carra carbon isotope records reflect land-use changes, paleoproductivity, carbon inputs, and the Suess Effect. This study demonstrates that lacustrine sedimentary d13C interpretations should consider diagenetic effects and be cognizant of potential significant spatial variability within a relatively small lake basin.