SUGARLOAF MOUNTAIN, CENTRAL ARIZONA: AN EXAMPLE OF MIOCENE ANDESITIC HYBRID MAGMA FORMED FROM ALKALIC BASALT AND CRUSTAL COMPONENTS
Results: Basalts have 47.2-49.1 wt.% SiO2 and 6.7-7.7 wt.% MgO, and they contain olivine (Fo73–86) and clinopyroxene (Fs8-13Wo45-49; Mg# 78-84) phenocrysts. Andesites (and dacite) have 61.4-63.9 wt.% SiO2 and 3.5-4.7 wt.% MgO. They also have olivine (Fo77–86) and clinopyroxene (Fs8-18Wo35-45; Mg# 73-86) phenocrysts, and additionally have quartz (0.2-3 vol. %), Na-plagioclase (An28-47; 3-6 vol. %), amphibole (Mg# 60-65), ± orthopyroxene (Fs22-35Wo2-3; Mg# 65-77), ± biotite (Mg# 60), ± Na,K feldspar (Ab33-42Or58-66). Notable for the andesites are (i) resorbed quartz, Na-plagioclase, and amphibole, and spongy zones and margins in and on Na-plagioclase cores, some with thin Na,Ca-plagioclase rims (An48-53), and (ii) some incompatible element abundances lower than those in the basalts (e.g., Ce 77-105 vs 114-166 ppm; Zr 149-173 vs 183-237; Nb 21-25 vs 34-42).
Conclusions: Sugarloaf basalt fractional crystallization alone cannot yield the andesites because (a) 61.4-63.9 wt.% SiO2 cannot be achieved at 3.5-4.7 wt.% MgO under any P or fO2 conditions (e.g., MELTS; mass-balancing), and (b) incompatible element abundances decrease with MgO evolving from ~7 to ~4 wt.%. However, the mineral assemblages, compositions, and textures are all consistent with basalt having mixed with rhyolitic magma or having assimilated crustal granitoid rock. Binary mixing (assimilation) calculations yield good results (R2 >0.99 for calculated vs actual major elements). For example, a hybrid mix of 73% average upper crust and 27% Sugarloaf basalt has an R2 ~0.999 fit for matching the major elements in a Sugarloaf andesite. Results suggest that Sugarloaf andesites formed by basalt incorporating SiO2-rich crustal material, but with the requirement that the SiO2-rich component had incompatible element concentrations lower than those observed in the hybrid andesite and dacite.