THE LARGEST OF THE CAMP INTRUSIONS: A GEOCHEMICAL AND ISOTOPIC STUDY OF THE FREETOWN LAYERED COMPLEX (SIERRA LEONE)
40Ar/39Ar dating of a plagioclase separate from one of the FLC gabbros gave an age of 202.3±2.4 Ma, which assigns this complex to the time of CAMP activity and the early stages of Pangea breakup and opening of the Central Atlantic Ocean.
Based on LA-ICPMS spot analyses of clinopyroxene and orthopyroxene crystals, the calculated trace element contents of the equilibrium melts indicate variously enriched and high-Ti compositions in agreement with those observed in the Liberia-FLC dyke swarm.
Except for three outliers, the intrusive rocks cluster in a tight range of 87Sr/86Sri (0.70337-0.70402) and 143Nd/144Ndi (0.51241-0.51252), at lower Nd for comparable Sr isotopic compositions relative to other high-Ti CAMP rocks from nearby Liberia, Guyana and northern Brazil in pre-drift reconstructions. Pb isotope systematics of the FLC show low 206Pb/204Pbi (17.520-17.850) and fall above the NHRL (207Pb/204Pbi = 15.549-15.594 and 208Pb/204Pbi = 37.730-37.936). A basaltic dyke and one gabbro plot towards the DMM field (with up to 0.70311, 0.51259, 0.28290, 17.702, 15.527, 37.651 for Sr, Nd, Hf and Pb isotopes, respectively). 176Hf/177Hfi (0.28279-0.28285), preliminary 188Os/187Osi (ca. 0.130), and previously published δ18O data for the FLC argue against significant crustal assimilation. These data rather suggest that the FLC derived from a mantle source dominated by an old (high Δ7/4Pb), EMI-flavored (low 206Pb/204Pb) component, while the subsequently emplaced dykes reflect substantial asthenospheric contribution.