URANIUM ISOTOPE EVIDENCE FOR PERVASIVE MARINE ANOXIA DURING THE LATE ORDOVICIAN MASS EXTINCTION
Bulk carbonate samples from the Upper Ordovician of Anticosti Island, Canada were analyzed to evaluate global marine redox patterns across the LOME. The Anticosti section was chosen because of its well-studied sequence and biostratigraphy and the fact that it has not been subjected to deep burial or tectonic processes. Isotopic analysis of bulk carbonates record relatively uniform values of ~0.10/00 across the Katian-Hirnantian boundary and into the mid-Hirnantian. The values then exhibit an abrupt negative shift to ~0.40/00 in the Late-Hirnantian, followed by a return to values of ~0.10/00 in the early Rhuddanian. This negative shift is roughly coincident with the second faunal turnover and is similar in magnitude to the shift reported across the end-Permian extinction. These results support earlier interpretations of widespread marine anoxia associated with the second faunal turnover; however they are at odds with recent interpretations of an intense anoxic event in the late Hirnantian-early Rhuddanian.
Given that the δ238 U signal recorded in marine carbonates reflects global versus local redox conditions they offer a more informative and flexible proxy which will greatly enhance our understanding of past changes in the chemistry of the oceans and their potential impacts on life.