SHELL WE DATE? ESR DATING MOLLUSCS FROM THE SANGAMONIAN INTERGLACIAL DEPOSITS AT HOPWOOD FARM, IL
Few geochronological methods can reliably date sites older than 50 ka. Since the Sangamonian at Hopwood Farm exceed the 14C dating limit, seven different absolute dating methods have been attempted at Hopwood Farm, without reaching a consensus about the age. For example, amino acid racemization (AAR) on molluscs, 230Th/234U on enamel and dentine, 231Pa/235U on dentine, ESR on tooth enamel, plus coupled ESR-230Th/234U and coupled ESR-231Pa/235U all yielded ages that did not agree well. Each method gave slightly, or drastically, different ages, ranging from 11 to 180 ka.
To solve the controversy, 14 mollusc samples newly collected with associated sediment from three depths at Hopwood Farm were dated by standard ESR. ESR can date molluscs from 0.5 ka to 2.6 Ma in age with 5-10% precision, by comparing the accumulated radiation dose with the total radiation dose rate from the mollusc and its environment. Because the molluscs had little U, their ages do not depend on the U uptake model. For Unit 3, the molluscs dated from 98-90 ± 6 ka, which correlates best with Marine Isotope Stage (MIS) 5c, or possibly, MIS 5b. These ESR ages also agreed well with the coupled ESR-230Th/234U ages on the teeth and the most recent AAR analyses on molluscs given their stratigraphic relationships.