GEOCHEMICAL AND SR, ND, AND OS ISOTOPIC SIGNATURES OF TARGET ROCKS AND IMPACTITES FROM THE ZHAMANSHIN CRATER, KAZAKHSTAN
Major and trace element data agree with derivation of impactites from the known suite of target rocks. Rare earth element abundances and patterns and Sr and Nd isotopic compositions support a connection between Cenozoic clays and irghizites and Si-rich zhamanshinites, whereas Si-poor zhamanshinites are related to basic and ultramafic target rocks. Rhenium/Os ratios in all impactites are consistently lower than in most target rocks, possibly reflecting selective Re-loss during impact. Chromium, Co, Ni, and HSE concentrations and the respective elemental distribution patterns of most target rocks and zhamanshinites mirror upper continental crust. In agreement with earlier work by other researchers, most irghizites have significantly higher Cr, Co, and Ni concentrations than target rocks and zhamanshinites. Concentrations of HSE in one of the analyzed irghizites exceeds those of the average target by two orders of magnitude, resulting in a less fractionated HSE pattern and near-chondritic interelement ratios; this sample also has a 187Os/188Os ratio that is significantly less radiogenic compared to most target rocks (~0.31 vs. 0.66 to 5.22, respectively). Excluding any ultramafic contaminant in this sample and interpreted in terms of a meteoritic admixture, this represents about 0.02% of a CI chondritic component