ENVIRONMENTAL RISK POTENTIAL OF TELLURIUM-RICH MINE TAILINGS IN A HISTORIC MINING DISTRICT IN DELAMAR, NEVADA
In this study, two distinct tailings piles were sampled as a function of depth. Extensive mineral weathering, indicated by sulfur X-ray absorption spectroscopy (XAS), influences metal(loid) speciation, which controls mobility and bioaccessibility. Tellurium and other toxic metal(loid)s, such as Cu and Pb, are enriched at the tailings surface, potentially as efflorescent salts or sorbed species. Physiologically-based extraction tests (PBETs) of surficial tailings with stomach fluids for Te, As, Cu, Pb, and Zn reveal bioaccessibility up to 10, 4, 19, 17, and 46%, respectively, indicating that these materials may be toxic if ingested. Aeolian transport, a dominant dispersion mechanism in semi-arid climates, has been demonstrated to disperse metal(loid)s at this site through sampling of surficial soils near the mill and tailings piles. Roughly 50% of tailings particles are wind transportable with diameters less than 37 µm and, if inhaled, PBETs indicate that 1, 7, 25, 0.01, and 0.3% of Te, As, Cu, Pb, and Zn, respectively, are bioaccessible. Tellurium bulk XAS indicate the predominance of Te(VI), which is less soluble and toxic than Te(IV), likely responsible for the low percentages of bioaccessible Te in the tailings. Taken together, these results lend insight into the potential health and environmental impacts of Te-rich mine tailings.