CONSTRAINTS ON THE THERMOBAROMETRIC EVOLUTION OF AMPHIBOLITES FROM THE SOUTHERN APPALACHIAN INNER PIEDMONT, WEST-CENTRAL GEORGIA
The amphibolites in this study are generally coarsely-layered, with alternating centimeter-scale bands of pargasitic amphibole + oligoclase-rich layers and epidote + quartz-rich layers. Peak conditions based on major-element exchange thermometers were previously estimated at 620-670 °C. To further quantify the PT path, in-situ accessory-phase thermobarometers (e.g. Zr-in-rutile, Zr-in-titanite) were then applied. The textural relationships of Ti- and Zr-bearing accessory phases (ilmenite, titanite, rutile, zircon) in these samples are well-characterized: titanites are abundant throughout the samples, contain epidote and amphibole as inclusions, and can be found as rims on rutile; rutile is only present as an inclusion within titanite; zircon, while not abundant, can be found both as inclusions and in the matrix. These relationships suggest that rutile grew during an earlier stage of the metamorphic history, while titanites grew at or near peak conditions. LA-ICP-MS analyses of rutile and titanite, conducted at The University of Texas at Austin, support this interpretation: Zr-in-rutile thermometry gives temperatures of 625 ± 35 °C, while Zr-in-titanite thermometry results cluster near 700 - 720 °C. Combined with thermobarometric models and construction of pseudosections, these data can help to resolve PT paths for the Southern Appalachians and refine tectonic models for orogenesis.