GREAT SALT LAKE (UTAH) MICROBIALITE CHRONOLOGY AND ISOTOPE GEOCHEMISTRY: IMPLICATIONS FOR PALEOLAKE EXTENT AND BIOGEOCHEMICAL EVOLUTION
Microbialite C (δ13CPDB) and O (δ18OPDB) stable isotope values covary significantly (R2=0.8) and range from 1.0 to 6.6 and -4.3 to -1.2 ‰, respectively. Aragonite ooids interpreted as modern have an average δ13CPDB = 3.9 and δ18OPDB = -3.9 ‰. Lake water collected at the time of microbialite sampling had a δ13CPDB of 2.0 ‰, and δ2HSMOW and δ18OSMOW of -59.5 and -3.4 ‰, respectively. Calculated aragonite values in equilibrium with lake water are similar to the ooid composition indicating that carbonate is likely forming in equilibrium with the lake water, and this is important for subsequent interpretation of the microbialite values. δ13CPDB and δ15NAIR values of organic matter vary from -18.4 to -13.6 ‰ and 6.3 to 10.1 ‰, respectively. Uncalibrated radiocarbon ages from extracted organic matter from core to rim in one microbialite are 9359, 9502, 10728, and 6747 yr BP. Associated mean calendar ages are 8640, 8920, 10733, and 5667 yr BCE. Currently, the magnitude of the reservoir effect on these ages is unknown. For comparison, the reservoir effect based on carbonate radiocarbon ages of modern GSL gastropods has been reported at 1 - 4.5 kyr, and this likely far exceeds the effect on organic matter ages. We suggest that C and O stable isotope data trends are tied to periods of lake level rise and fall with implication for resolving Holocene variations in the lake hydrograph and biogeochemistry.