FLUID INCLUSIONS IN QUARTZ AND STIBNITE FROM THE YELLOW PINE DEPOSIT OF IDAHO
Cathodoluminescence (CL) textures show a paragenesis beginning with igneous phenocrysts cut by pre-ore aqueous-carbonic inclusions, followed by a complex series of hydrothermal events involving intermittent quartz + sulfide ± sericite deposition within well zoned hydrothermal quartz, overprinted by bright CL quartz associated with stibnite. The inclusions in quartz related to metal bearing hydrothermal activity yield Th of 175-233°C, Ph of 9-28 bars, salinities of 6-9 wt. % NaCl, and low contents of CO2 ± CH4.
The stibnite is commonly highly fractured, in which case it generally lacks visible inclusions. In unfractured stibnite crystals, four inclusion populations have been observed at room temperature; including one with both liquid- and vapor-rich inclusions. Microthermometry on what are considered primary inclusions in stibnite give Th of 160 to 189°C, Ph of 6-11 bars, salinities of 4-11 wt. % NaCl, and no gases.
The homogenization temperatures and pressures from ore-stage quartz and stibnite indicate that mineralization at YP formed in a shallow epizonal environment. The differences between inclusions in quartz and stibnite indicate that decompression and cooling caused stibnite precipitation.