GSA Annual Meeting in Indianapolis, Indiana, USA - 2018

Paper No. 184-19
Presentation Time: 9:00 AM-6:30 PM

QUANTITATIVE LACUSTRINE PALEOSALINITY AND PLEISTOCENE ORBITAL CONTROLS FROM CLAY MINERAL OXYGEN ISOTOPES: OLDUVAI GORGE, TANZANIA


GEBREGIORGIS, Daniel1, DEOCAMPO, Daniel M.1, LONGSTAFFE, Fred J.2, ASHLEY, Gail M.3, BEVERLY, Emily J.4, DELANEY, Jeremy S.3 and CUADROS, Javier5, (1)Department of Geosciences, Georgia State University, 24 Peachtree Center Ave NE, Atlanta, GA 30303, (2)Department of Earth Sciences, The University of Western Ontario, 1151 Richmond Street, Biological and Geological Sciences Building, London, ON N6A 5B7, Canada, (3)Earth and Planetary Sciences, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, (4)Department of Earth & Environmental Sciences, University of Michigan, 1100 North University Avenue, Ann Arbor, MI 48109, (5)Department of Earth Sciences, Natural History Museum, Cromwell Road, London, SW7 5BD, United Kingdom

Few proxies quantitatively record important paleolimnological parameters such as temperature and salinity. Because lake hydrology is at times driven by non-climatic factors, such as basin morphology, deciphering climate history from lake sediments is complex. As a consequence, paleoclimate proxies within closely allied lake systems often respond independently to high and low frequency climate variability. This is particularly true in the case of sedimentary records from active tectonic settings.

In East African lakes, elevated salinity and alkalinity commonly leads to authigenic clay minerals enriched in Mg. Here we use isotopic measurements of structural oxygen in authigenic clay minerals (δ18OC) in the Olduvai Basin to extract the salinity signal and generate the first record of paleolake water salinity for the early Pleistocene (~1.8 – 1.92 Myrs). We first caclculate the δ18O of the paleolake water (δ18OLW) by applying equilibrium fractionation constants based on X-ray diffraction and assuming 25˚C. Paleolake water salinity (Total Dissolved Solids, g/L) is then calculated according to TDS=(0.3× δ18OLW)+1.64, a relationship based on paired measurements of modern δ18OLW and TDS in meteoric surface waters at Ngorongoro Crater (Deocampo, 2004).

Our results show that during the early Pleistocene, the clay minerals were in equilibrium with paleolake waters ranging between –4.5 and –1.5‰ (VSMOW) and this corresponds to a TDS range of 0.3 to 1.2 g/L. Although the paleosalinity record is not strictly consistent with geochemical indicators of freshening (Al2O3/MgO) from the same site (Deocampo et al., 2017), intervals of low salinity coincide with high Al2O3/MgO values. The new proxy faithfully captures all events of significant freshening and reveals that enhanced East African monsoon precipitation was sensitive to warming over high latitudes in the Southern Hemisphere. These changes were the main drivers of changing terrestrial habitats, providing resources and hazards to hominins and other vertebrates, and setting the stage of environmental variability and the evolution of early hominins (e.g. Behrensmeyer, 2006).

References

Deocampo, D.M., 2004. Applied Geochemistry: 19, 755–767.

Deocampo et al., 2017. Geology: 45 (8), 683-686.

Behrensmeyer, A. K., 2006. Science: 311, 476-478.