FINGERPRINTING CRUSTAL FOUNDERING IN THE NORTHERN ANDEAN VOLCANIC ZONE USING BASALT GEOCHEMISTRY
Here, primitive basalt geochemistry is used to investigate the nature of this eruption by tracing the potential source(s) of magma generation. Major and trace element concentrations were obtained by XRF and LA-ICP-MS for 13 juvenile lava bombs within pyroclastic flows of the Granatifera Tuff, all of which host garnet-free and garnet-bearing peridotite, pyroxenite, and hornblendite xenoliths. Based on their SiO2 contents, all bombs are classified as basalts to basaltic andesites, and the most primitive samples (n = 5) are characterized by MgO wt. % > 7.7, Mg# > 60, and have high concentrations of Cr (181-285 ppm) and Ni (136-234 ppm), indicating they represent primary or near-primary magmas. Zn/FeT (*104) ratios (12.9 – 13.7) fall well above the average for melts derived from normal peridotite (8.5) and even extreme peridotite (11), thus requiring a significant component of pyroxenite-derived melts in their source. We argue that basalts of the Granatifera Tuff record the contribution of pyroxenite-derived melts to arc magmatism in this section of the northern Andean volcanic zone and presumably formed as lower-crust garnet pyroxenites surpassed their solidus near the base of the arc-crust and/or during gravitational descent into the mantle. These observations are in agreement with geochemical and thermobarometric data from abundant garnet clinopyroxenite xenoliths found in this eruption, and also bear close geochemical similarities with lavas previously interpreted as recording lower crustal foundering under the Puna Plateau in the Central Andes.