CRYSTAL GROWTH OF ILLITE IN PENNSYLVANIAN SHALE OF THE AMERICAN MID-CONTINENT REGION – SMECTITE PRECURSOR AND POSSIBLE IMPLICATIONS FOR PHYSICOCHEMICAL PROPERTIES OF UNCONVENTIONAL RESERVOIRS
In order to shed more light on crystal growth processes and clay mineral composition of shale matrix, an integrated study using different methodology was designed. Samples of Paleozoic shale of the Anadarko Basin were cored at depths from 2000 to 4200 m. Based on comparative mineralogical data - X-ray diffraction, electron microscopy and Infrared Attenuated Total Reflectance - and K-Ar age investigation performed on four illite fractions (2-1 μm , <2 μm, <1 μm, and <0.2 μm), we report on the mineralogical composition of shale matrix at different scales and mechanism of crystal growth of illite. Our integrated results show the finest fraction to be younger and to contain more smectite component than the coarser ones.
Our mineralogical and isotopic data suggest I-S as the dominant clay phase with up to 20% of smectite component, which underwent progressive illitization upon burial, essentially controlled by solid-state transformation processes. Such findings must be considered in the context of exploitation purposes, since characteristics that are inherent to these clay materials (i.e. I-S), including morphology and particle size, ion exchange properties, swelling and dispersion noticeably differ from pure illitic phase.