RECONSTRUCTION OF PALEOENVIRONMENTAL CONDITIONS AND TEMPORAL PATTERNS OF ANCIENT MINING ON ISLE ROYALE USING BIOGEOCHEMICAL ANALYSES OF LAKE SEDIMENT
In 2016, we collected a 7.5 m long sediment core sequence from Lily Lake on Isle Royale, MI. Lily Lake lies approximately 100 m above the current water level of Lake Superior, and formed approximately ~11,000 years before present following the retreat of the Laurentide ice sheet. Lily Lake has been exposed to very little human land use change relative to other lakes on Isle Royale (e.g. there are no ancient pit mines in the immediate catchment), and thus is well suited for reconstructing past environmental changes. We analyzed weakly sorbed metal concentrations using ICP-MS to test hypotheses on the timing and transport mechanisms of potential metal pollution derived from ancient mining activities. In addition, we conducted EA-IRMS analysis (including carbon/nitrogen ratios, and the isotopic composition of organic C and N) on bulk organic sediment to provide a record of natural paleoenvironmental changes.
Results from the metals analysis provide evidence of Middle Archaic mining activity that is temporally consistent with radiocarbon dated artifacts and similar evidence from other lakes located adjacent ancient pit mines on Isle Royale and the Keweenaw Peninsula of Michigan. Additional work is required to assess the relative influence of natural versus anthropogenic processes that may have influenced metal concentrations in Lily Lake sediment and to determine a transport mechanism for the putative mining related pollution.