MINERALOGY AND HISTORY OF SEMI-PRECIOUS GEMSTONES ON THE BORGHESE-WINDSOR CABINET (Invited Presentation)
Agates are composed of silica, mainly as the mineral quartz, but also as metastable moganite. Both quartz and moganite will crystallize together as the agate forms, but moganite will convert to quartz over tens of millions of years; thus, relatively older agate contains less moganite, and this ratio can be measured with a variety of analytical techniques.
The agate gemstones of the Borghese-Windsor Cabinet cannot be removed for detailed Raman or XRD mineralogical analyses. Because of this, we first analyzed agate specimens of known provenance from the collections of the Natural History Museum of Los Angeles County (NHMLAC) and the Smithsonian Institution National Museum of Natural History (NMNH) using three different techniques: Raman mapping, micro-XRF mapping, and visible-shortwave infrared hyperspectral imaging (HSI). After correlating Raman/XRF and HSI data, we performed in situ HSI of the entire cabinet. From these data, it was determined that the much of agate on the cabinet is likely from Idar-Oberstein, but a significant portion was either originally sourced from a different locality, or possibly replaced at a later date.