REEXAMINING THE ORDOVICIAN-SILURIAN BOUNDARY OF EASTERN NORTH AMERICA
Previous geochemical investigations of the Manitoulin Formation in Ontario by Bergström et al. revealed a positive δ13Ccarb excursion, hypothesized to be the Hirnantian Isotopic Carbon Excursion or HICE. Our investigations continued to explore the Manitoulin and laterally equivalent strata that surround the current Ordovician and Silurian boundary in eastern North America. Detailed measurements and carbonate sampling were undertaken to identify δ13Ccarb excursions, such as the HICE, and to correlate them across the region. Carbonate samples were collected from both drill core and outcrop that span across Indiana, Ohio, Kentucky, New York and Ontario. Sections in southern Ohio and Kentucky revealed a δ13Ccarb excursion in the Centerville Member, which has been hypothesized to be the HICE. Extensive sampling through large sections of drill core also permitted the identification of a series of globally recognized Late Ordovician δ13Ccarb excursions in the local stratigraphic record. Preliminary chemostratigraphic and sequence stratigraphic correlations of outcrop and drill core indicate the existence of a thin succession of Hirnantian strata sandwiched between two significant unconformities in eastern North America. The strata with a putative HICE signature include the Manitoulin Formation (in part), Whirlpool Sandstone, and Centerville Member of the Whippoorwill Formation, all previously assigned a lower Silurian age. These form a thin but distinctive depositional sequence reflecting a Hirnantian glacioeustatic transgression.