FORMATION AND EVOLUTION OF THE PROTOLUNAR DISK AND THE MAGMA OCEAN
We study the formation and condensation of the disk and the evolution of the MO using molecular dynamics simulations based on ab initio calculations. We work on a multi-component silicate fluid with bulk silicate Earth composition. From the pressure-density variation and the Maxwell construction, we determine the limits of stability of the molten silicate and the position of the critical point. We find that the Earth’s protolunar disk reached the supercritical state of the silicate mantle. Then we follow the chemical evolution of the disk during its cooling.
We characterize the structure and behavior of the MO. The onset of a mushy layer rich in bridgmanite crystals profoundly marks its evolution. This layer exhibits neutral buoyancy and effectively separates the MO at middle depths into a shallow MO and a basal MO that evolve separately.
We also characterize the composition of the disk atmosphere and find that it is extremely rich in molecules. Oxidized phases like SiO, O, O2, MgO, and cations like Na and Mg dominate the gas phase. But a plethora of other phases are present in the system, with lifetimes that allow them to play a role in the chemical and isotopic exchanges. Many of the gas molecules that we find in our simulations are not present in databases like JANAF. This suggests that a huge field of investigation lies bare ahead of us.